1239744-63-8Relevant academic research and scientific papers
Selective labeling of living cells by a photo-triggered click reaction
Poloukhtine, Andrei A.,Mbua, Ngalle Eric,Wolfert, Margreet A.,Boons, Geert-Jan,Popik, Vladimir V.
, p. 15769 - 15776 (2009)
Phototriggering of the metal-free azide to acetylene cycloaddition reaction was achieved by masking the triple bond of dibenzocyclooctynes as cyclopropenone. Such masked cyclooctynes do not react with azides in the dark. Irradiation of cyclopropenones res
Cyclopropenones and the Photochemical Generation of Cyclic Alkynes Therefrom
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Page/Page column 14-15; 17, (2010/08/22)
Cyclic alkynes (e.g., cyclooctynes such as dibenzocyclooctynes) can be photochemically generated from cyclopropenones as disclosed herein. The cyclic alkynes can be reacted (e.g., in situ) with materials having alkyne-reactive groups (e.g., azide groups i
