123993-77-1

Upstream product

• 18522-92-4 sodium p-toluenesulfonamide 
• 124095-79-0 (E)-(R*,R*)-5-chloro-3-hexen-2-yl acetate 
• 123993-66-8 (2S*,5S*)-2-acetoxy-5-(tosylamido)-3-hexene 

Downstream Products

• 123993-85-1 N-((1R,4R)-4-Hydroxy-1-methyl-pentyl)-4-methyl-benzenesulfonamide 
• 143707-53-3 (2S*,3R*,4S*,5S*)-3,4-epoxy-5-(tosylamido)hexan-2-ol 
• 143707-53-3 (2S*,3S*,4R*,5S*)-3,4-epoxy-5-(tosylamido)hexan-2-ol 
• 123993-93-1 Methanesulfonic acid (1R,4R)-1-methyl-4-(toluene-4-sulfonylamino)-pentyl ester 
• 123993-97-5 trans-N-(p-toluenesulfonyl)-2,5-dimethylpyrrolidine 
• 81330-01-0 cis-N-(p-toluenesulfonyl)-2,5-dimethylpyrrolidine 
• 143707-50-0 (2S*,5S*)-2-<(tert-butyldimethylsilyl)oxy>-5-(tosylamido)-3-hexene 

Relevant academic research and scientific papers

Epoxidation of 5-(Tosylamido)-3-hexen-2-ol Derivatives. Stereochemical Assignment of Product Configuration by NMR and Molecular Mechanics Studies

Epoxidation of syn- and anti-5-(tosylamido)-3-hexen-2-ol derivatives was studied using three different epoxidation reagents: (i) m-CPBA, (ii) t-BuOOH/VO(acac)2, and (iii) t-BuOOH/Ti(O-i-Pr)4.A method for the stereochemical assignment of the 3,4-epoxy-5-(tosylamido)-3-hexen-2-ol derivatives obtained was developed by the use of NMR spectroscopy.

A Stereocontrolled Organopalladium Route to 2,5-Disubstituted Pyrrolidine Derivatives. Application to the Synthesis of a Venom Alkaloid of the Ant Species Monomorium latinode

A general method for the preparation of cis- and trans-2,5-disubstituted pyrrolidines from conjugated dienes has been developed.The approach involves a stereocontrolled syn- or anti-1,4-addition of an amino and an oxygen function to the diene via palladiu