1239969-17-5Relevant articles and documents
Selective propargylation of AZO compounds with barium reagents
Yanagisawa, Akira,Koide, Takanori,Yoshida, Kazuhiro
, p. 1515 - 1518 (2010)
A Barbier-type propargylation of azo compounds with γ- trialkylsilylated propargylic bromides has been achieved using reactive barium as a low-valent metal in THF. Corresponding propargylated hydrazines (α-adducts) were exclusively formed not only from azobenzenes (diaryldiazenes) but also from dialkyl azodicarboxylates. This method is also applicable to -alkylated or γ-phenylated propargylic bromides, providing the desired propargylated products only. Georg Thieme Verlag Stuttgart New York.