1239972-46-3Relevant academic research and scientific papers
Iridium-catalyzed asymmetric hydrogenation of β-ketophosphonates with chiral ferrocenyl P,N,N-ligands
Ma, Yin-Feng,Hou, Chuan-Jin,Wei, De-Quan,He, Xinwei,Chu, Ting-Ting,Chen, Xiu-shuai,Hu, Xiang-Ping
, (2021)
The asymmetric hydrogenation of β-ketophosphonates with chiral Ir/P,N,N-ligands catalyst has been developed. A series of β-ketophosphonates were hydrogenated, and the corresponding β-hydroxyphosphonates were obtained in high yields with good or excellent
Nonenzymatic kinetic resolution of racemic β-hydroxyalkanephosphonates with a chiral copper catalyst
Moriyama, Atsushi,Matsumura, Shintaro,Kuriyama, Masami,Onomura, Osamu
experimental part, p. 810 - 824 (2010/11/04)
Kinetic resolution of β-hydroxyalkanephosphonates was efficiently performed by 2-fluorobenzoylation in the presence of copper(II) triflate and (R,R)-Ph-BOX as a catalyst with good s value of up to 21.
