1240047-86-2

Basic information

• Product Name: (o-Tol)C(C₆H₄-p-CF₃)C(SnMe₃)(C₆H₄-p-OMe)
• CAS NO: 1240047-86-2
• Molecular Weight: 531.205
• Mol File: 1240047-86-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (o-Tol)C(C₆H₄-p-CF₃)C(SnMe₃)(C₆H₄-p-OMe)(CAS DataBase Reference)
• NIST Chemistry Reference: (o-Tol)C(C₆H₄-p-CF₃)C(SnMe₃)(C₆H₄-p-OMe)(1240047-86-2)
• EPA Substance Registry System: (o-Tol)C(C₆H₄-p-CF₃)C(SnMe₃)(C₆H₄-p-OMe)(1240047-86-2)

Safety Data

• Hazardous Substances Data: 1240047-86-2(Hazardous Substances Data)

Upstream product

• 17946-71-3 (trimethylstannyl)lithium 
• 455-13-0 4-Iodobenzotrifluoride 
• 59105-21-4 1-methoxy-4-(2-(2-tolyl)ethynyl)benzene 

Relevant articles and documents

Synthesis of tetrasubstituted alkenes by stereo- and regioselective stannyllithiation of diarylacetylenes

Addition of trimethylstannyllithium to a diarylacetylene takes place exclusively in an anti-fashion to produce a lithio vinylstannane intermediate. The regioselectivity of the addition is controlled by the steric and electronic property of the acetylene and reaches up to >99:1. The two newly formed C-metal bonds can be sequentially and stereospecifically transformed into two new C-C bonds as illustrated by stereoselective synthesis of 4-hydroxytamoxifen and its regioisomer. A tetraarylethene bearing different aryl groups can be synthesized similarly and cyclized to a substituted dibenzo[g,p]chrysene derivative via a palladium-catalyzed arylation reaction.