124010-25-9Relevant academic research and scientific papers
A NEW ROUTE TO 4-OXYGENATED ISOXAZOLINES. APPLICATION TO THE SYNTHESIS OF 2-DEOXY-2-AMINOBUTOSE DERIVATIVES
Wade, Peter A.,Price, David T.
, p. 1185 - 1188 (1989)
The THP ether of 4,5-dihydro-3-nitro-4-isoxazol, prepared by a sequential nitroaldol nitrosative cyclization strategy, was converted to a 4,5-dihydro-3-(dithiolanyl)isoxazole; subsequent LBH reduction gave a 95:5 diastereomeric mixture of 2-deoxy-2-aminot
2-Amino-2-deoxytetrose derivatives. Preparation from 4,5-dihydroisoxazoles via reductive cleavage
Wade,D'Ambrosio,Price
, p. 6302 - 6308 (2007/10/03)
The 4-alkoxy-3-nitro-4,5-dihydroisoxazoles 2a,b were prepared by condensation of nitromethane and chloroacetaldehyde, protection of the resulting nitroaldol 1c, and subsequent nitrosative cyclization. Multistep replacement of the nitrogroup of 2a,b by a 2
