1240290-62-3Relevant academic research and scientific papers
A recyclable fluorous thiourea organocatalyst for the chemoselective oxidation of sulfides
Huang, Yi-Bo,Yi, Wen-Bin,Cai, Chun
, p. 554 - 557 (2011)
As a kind of organocatalyst, 1-[4-(perfluorooctyl)phenyl]-3-phenylthiourea was employed to the chemoselective oxidation of sulfides in the presence of 30% H2O2. A variety of diaryl, dialkyl, alkyl aryl sulfides could be oxidized to s
An efficient, recoverable fluorous organocatalyst for direct reductive amination of aldehydes
Huang, Yi-Bo,Yi, Wen-Bin,Cai, Chun
experimental part, p. 879 - 882 (2010/10/01)
A commercially available perfluorooctyl aniline and phenyl isothiocyanate were reacted under mild conditions to give 1-[4-(perfluorooctyl)phenyl]-3- phenylthiourea as an analogue of thiourea-based organocatalyst. This fluorous organocatalyst was successfully employed to direct reductive amination of aldehydes. It could be readily separated from reaction product by fluorous solid phase extraction for direct use.
