124044-22-0Relevant academic research and scientific papers
Studies toward the synthesis of natural and unnatural dienediynes 1. Approaches to a functionalised bicyclic ring system
Caddick,Delisser,Doyle,Khan,Avent,Vile
, p. 2737 - 2754 (2007/10/03)
The synthesis of a functionalised bicyclic ring system related to the naturally occurring dienediynes, NCS and Kedarcidin Chromophores is presented. Key steps involve: conjugate addition of an enediyne to a functionalized enone and intramolecular boron mediated aldol reaction.
Studies on the thermal generation and reactivity of a class of (σ,π)-1,4-biradicals
Myers, Andrew G.,Dragovich, Peter S.,Kuo, Elaine Y.
, p. 9369 - 9386 (2007/10/02)
(Z)-1,2,4-Heptatrien-6-yne and compounds that contain the (Z)-allene-ene-yne functional group or that form it in a serial reaction sequence were prepared and shown to undergo a mild thermal reaction to form aromatic products. All observations suggest that
VERSATILE PRECURSORS FOR THE SYNTHESIS OF ENYNES AND ENEDIYNES
Myers, Andrew G.,Alauddin, Mian M.,Fuhry, Mary Ann M.,Dragovich, Peter S.,Finney, Nathaniel S.,Harrington, Philip M.
, p. 6997 - 7000 (2007/10/02)
(Z)-Ethyl 2,3-dibromopropenoate, readily available in multigram quantities, undergoes selective replacement of the β-bromide in coupling reactions with trimethylsilylacetylene to produce the (Z)-enyne 2.This product may be further elaborated to various fu
