1240507-76-9Relevant articles and documents
Luminescent chiral organoboron 8-aminoquinolate-coordination polymers
Tokoro, Yuichiro,Nagai, Atsushi,Chujo, Yoshiki
, p. 563 - 568 (2010)
We have successfully synthesized optically active organoboron aminoquinolate-based coordination polymers bearing the chiral side chain derived from L-alanine, and studied their optical behavior by UV-vis and photoluminescence spectroscopies. Higher absolute quantum yields (φF) of the obtained polymers, measured by integrating sphere method, were observed with electron-withdrawing substituent (φF = 0.80) than with electron-donating substituent (φF = 0.52). The circular dichroism (CD) study in the mixed solvents of CHCl3 and DMF showed that the secondary structures of the obtained polymers were stabilized by hydrogen-bonding interaction in the side chain. From concentration dependence on the CD spectra, the chirality of the obtained polymers originated from the nature of one molecule. Copyright