1240781-41-2Relevant academic research and scientific papers
Stereoselective syntheses of trisubstituted olefins via platinum catalysis: α-Silylenones with geometrical complementarity
Rooke, Douglas A.,Ferreira, Eric M.
supporting information; experimental part, p. 11926 - 11928 (2010/11/16)
The stereoselective syntheses of α-silylenones using catalytic PtCl2 are reported. Via alkyne activation, α- hydroxypropargylsilanes are converted to (Z)-silylenones through a highly selective silicon migration. The complementary (E)-silylenone
