124128-13-8Relevant academic research and scientific papers
Synthesis and reactivity of dipropargylic disulfides: tandem rearrangements, cyclization, and oxidative dimerization
Braverman, Samuel,Cherkinsky, Marina,Meridor, David,Sprecher, Milon
scheme or table, p. 1925 - 1930 (2010/04/24)
Synthesis and facile rearrangement and cyclization reaction of new dipropargylic disulfides are described. A possible mechanism for these transformations involving an initial double [2,3]-sigmatropic rearrangement to the elusive diallenyl disulfides via a thiosulfoxide intermediates is suggested.
Experimental and Theoretical Study of the Radical-Chain Addition of Benzenethiol to Heterosubstituted Allenes
Pasto, Daniel J.,L'Hermine, Gael
, p. 685 - 694 (2007/10/02)
The radical-chain addition of benzenethiol to phenylallene (PHA), methoxyallene (MEOA), carbomethoxyallene (CBA), cyanoallene (CNA), chloroallene (ClA), and (phenylthio)- and allene (PHSA and MPHSA) has been studied.In all cases, exc
CINETIQUE ET MECANISME DE LA REACTION DE PROTOTROPIE DES COMPOSIES PROPARGYLIQUES, ALLENIQUES ET PROPYNYLIQUES PORTANT UN HETEROATOME (COLONNE Vb ET VIb)
Pourcelot, G.,Cadiot, P.,Georgoulis, C.
, p. 2123 - 2128 (2007/10/02)
A detailed kinetic study of the prototropic rearrangement of the system RMCH2-CCHRM-CH=C=CH2RM-CC-CH3 where M=NR, O, S, Se is presented.Using deuterated substrates the nature of the reactive intermediates and, in the case of M=S, the activatio
