124128-41-2Relevant academic research and scientific papers
Asymmetric Catalysis, LI. - New Optically Active Chelating Phosphines - Synthesis and Application in Enantioselective Catalysis
Brunner, Henri,Lautenschlager, Hans-Juergen,Koenig, Wilfried A.,Krebber, Ralph
, p. 847 - 853 (2007/10/02)
The known triphosphines 1 and 4 were transformed into their monophosphine oxide and monophosphine sulfide derivatives 2, 3, 5, and 6 via NiCl2 complexes. 21 optically active phosphines were used as ligands in the Rh-catalysed hydrogenation of (Z)-α-acetam
