124200-45-9Relevant academic research and scientific papers
Synthesis and Characterization of New Style of Water-Soluble Glycosylated Porphyrins as a Spectrophotometric Reagent for Metal Ions
Kohata, Katsunori,Higashio, Hisao,Yamaguchi, Yuichi,Koketsu, Mamoru,Odashima, Tsugikatsu
, p. 668 - 679 (2007/10/02)
Six new styles of water-soluble glycosylated porphyrins (5,10,15,20-tetrakisporphine) were synthesized and studied concerning their structures by 1H and 13C NMR.Tetrakis (o-substituted phenyl)porphine, consisting of four atropoisomers (αβαβ, ααββ, αααβ, and αααα), was clearly assigned based on the 13C NMR peak-splitting pattern.It was especially noteworthy that water-soluble picket-fence porphyrin (αααα) was obtained.Furthermore, their characterization as a chromogenic reagent for metal ions was investigated.The introduction of highly water-soluble glucose successfully improved the aggregration and adsorption characteristics of the anionic or cationic porphyrins so far prepared without any marked change in the other important analytical properties.
