1242069-38-0Relevant articles and documents
2-[(Neopentyl glycolato)boryl]phenyl Triflates and Halides for Fluoride Ion-Mediated Generation of Functionalized Benzynes
Ikawa, Takashi,Yamamoto, Rika,Takagi, Akira,Ito, Toyohiro,Shimizu, Kazunori,Goto, Masahiko,Hamashima, Yoshitaka,Akai, Shuji
, p. 2287 - 2300 (2015/07/27)
2-[(Neopentyl glycolato)boryl]phenyl trifluoromethanesulfonates (triflates) and halides have been developed as new benzyne precursors, which generate benzynes at 120°C in the presence of a fluoride ion. There are two major features of these types of precu
An alkynylboronate cycloaddition strategy to functionalised benzyne derivatives
Kirkham, James D.,Delaney, Patrick M.,Ellames, George J.,Row, Eleanor C.,Harrity, Joseph P. A.
supporting information; experimental part, p. 5154 - 5156 (2010/10/19)
A new approach to benzyne precursors has been developed that involves the [4+2] cycloaddition of trimethylsilyl alkynylboronates with 2-pyrones, followed by oxidation and trifluoromethylsulfonylation of the boronate moiety. The Royal Society of Chemistry