1242076-77-2Relevant academic research and scientific papers
Asymmetric total synthesis of trilobacin via organoselenium-mediated oxonium ion formation/SiO2-Promoted fragmentation
Sohn, Te-Ik,Kim, Mi Jung,Kim, Deukjoon
supporting information; experimental part, p. 12226 - 12227 (2010/10/21)
An asymmetric total synthesis of trilobacin (1), an annonaceous acetogenin with potent anticancer activities, was accomplished wherein the construction of its erythro-bis(2,2′)-tetrahydrofuran core 2 featured a novel organoselenium-mediated oxonium ion formation/SiO2-promoted fragmentation of α,α′-cis-oxocene 3.
