1242099-22-4Relevant academic research and scientific papers
C 1-symmetric dicyclopentadienes as new chiral diene ligands for asymmetric rhodium-catalyzed arylation of N-tosylarylimines
Shao, Cheng,Yu, Hong-Jie,Wu, Nuo-Yi,Feng, Chen-Guo,Lin, Guo-Qiang
supporting information; experimental part, p. 3820 - 3823 (2010/10/21)
Monosubstituted C1-symmetric dicyclopentadienes as a new class of diene ligands have been developed for asymmetric arylation of N-tosylarylimines in excellent yields (98-99%) with high enantioselectivities (90-96%). The preparation of these diene ligands relied on an efficient lipase-catalyzed resolution as the key step.
