1242159-31-4Relevant academic research and scientific papers
Asymmetric synthesis of highly enantioenriched 2-substituted piperidines and 6-substituted piperidine-2-ones by a combination enantioselective hydrazone allylation with ring closing metathesis
Piao, Fengnu,Mishra, Mithilesh Kumar,Jang, Doo Ok
experimental part, p. 7050 - 7055 (2012/08/28)
An efficient method for the asymmetric synthesis of highly optically pure 2-substituted piperidines and 6-substituted piperidine-2-ones from aldehydes was developed by a sequence of enantioselective hydrazone allylation and ring closing metathesis. This m
Indium-mediated catalytic enantioselective allylation of N -benzoylhydrazones using a protonated chiral amine
Kim, Sung Jun,Jang, Doo Ok
supporting information; experimental part, p. 12168 - 12169 (2010/10/03)
A catalytic enantioselective indium-mediated allylation of N-benzoylhydrazones in conjunction with a protonated chiral amine affording enantioenriched homoallylic amines with an extremely high level of enantioselectivity and chemical yield was developed.
Indium(I)-catalyzed asymmetric allylation, crotylation, and αchloroallyalation of hydrazones with rare constitutional and high configurational selectivities
Chakrabarti, Ananya,Konishi, Hideyuki,Yamaguchi, Miyuki,Schneider, Uwe,Kobayashi, Shu
supporting information; experimental part, p. 1838 - 1841 (2010/06/17)
The hydra-zone: The first example of asymmetric In catalysis had been developed. In I combined with a chiral semicorrin ligand (L*) is an effective catalyst for enantioselective allylation, crotylation and α-chloroallylation of hydrazones. In the two latter cases, C-C bond formations proceeded with high selectivity where both reactive aliphatic C-Cl and aromatic O-H bonds were tolerated. Chemical equation representation
