1242174-75-9Relevant academic research and scientific papers
Asymmetric synthesis of γ-hydroxy α-enones by 1,8-diazabicyclo[5.4.0]undec-7-ene-catalyzed stereoselective rearrangement of chiral α-sulfinyl enones
Miura, Motofumi,Toriyama, Masaharu,Kawakubo, Takashi,Yasukawa, Ken,Takido, Toshio,Motohashi, Shigeyasu
supporting information; experimental part, p. 3882 - 3885 (2010/11/18)
The asymmetric rearrangement of optically active α-sulfinyl enone 1 induced by catalytic DBU and triphenylphosphine gave optically active γ-hydroxy α-enone derivatives (up to 99% ee) in good yield following treatment with aqueous hydrogen peroxide.
