1242247-76-2Relevant academic research and scientific papers
Synthesis and antioxidant activity of a novel class of 4,6-O-protected O-glycosides and their utility in disaccharide synthesis
Rajaganesh, Ramanathan,Jayakumar, Jayaraman,Sivaraj, Chandrasekaran,Raaman, Nanjian,Das, Thangamuthu Mohan
experimental part, p. 1649 - 1657 (2010/10/04)
BF3·Et2O-catalysed O-glycosylation of 1,2,3-tri-O-acetyl-4,6-O-butylidene- and ethylidene-β-d-glucopyranose with different aliphatic and aromatic alcohols proceeds for the most part with complete retention of anomeric configuration. Antioxidant activity of O-glycosides shows significant inhibition (IC50 ～77%). 1,3-Dipolar cycloaddition of terminal alkyne derivatives of O-glycosides with glycosyl azide results in disaccharides.
