124237-03-2Relevant academic research and scientific papers
ANOTHER LOOK AT THE PHOTODECHLORINATION OF BROMODAN
Turner, Walter V.,Gaeb, Siegmar
, p. 3711 - 3716 (2007/10/02)
Contrary to a previous report, there is no solvent-dependent selectivity to either of the double-bond-dechlorinated derivatives when Bromodan is irradiated in hexane or methanol.The 7-dechlorinated derivative formed on photolysis in triethylamine is debrominated on further irradiation. 13C chemical shifts and longe-range C-H coupling constants indicate that the structural assignment of the double-bond-dechlorinated isomers mest be reversed.
