1242418-75-2Relevant academic research and scientific papers
Stereocontrolled synthesis of the highly functionalized core structure of aurisides by ring-closing metathesis
Bourcet, Emmanuel,Fache, Fabienne,Piva, Olivier
experimental part, p. 4075 - 4087 (2010/10/02)
Two approaches based on the ring-closing metathesis reaction have been explored for the synthesis of the core structure of the marine natural products, the aurisides. The second approach, accomplished in a stereocontrolled manner, used both a Brown's allylation and an Evans' aldolisation, and finally a transannular ketalization to deliver a highly functionalized auriside analogue.
