1242430-53-0Relevant articles and documents
The first enantioselective synthesis of cytotoxic marine natural product palau'imide and assignment of its C-20 stereochemistry
Lan, Hong-Qiao,Ruan, Yuan-Ping,Huang, Pei-Qiang
supporting information; experimental part, p. 5319 - 5321 (2010/09/03)
Methyl tetramate derivative 6 has been developed as a new building block for the flexible and racemization-free synthesis of methyl 5-benzyl-3- methyltetramate via alkylation, and used in the first asymmetric synthesis of palau'imide (1). This allowed the establishment of the hitherto unknown stereochemistry at the C-20 of palau'imide as S.