124285-98-9Relevant academic research and scientific papers
Shifted Selectivity in Protonation Enables the Mild Deuteration of Arenes through Catalytic Amounts of Bronsted Acids in Deuterated Methanol
Fischer, Oliver,Hubert, Anja,Heinrich, Markus R.
, p. 11856 - 11866 (2020/10/23)
Taking advantage of the "differentiating effect"of the solvent methanol, deuterations of electron-rich aromatic systems can be carried out under mild acid catalysis and thus under far milder conditions than known so far. The exceptional functional group t
Steric isotope effects gauged by the bowl-inversion barrier in selectively deuterated pentaarylcorannulenes
Hayama, Tomoharu,Baldridge, Kim K.,Wu, Yao-Ting,Linden, Anthony,Siegel, Jay S.
, p. 1583 - 1591 (2008/09/18)
Motivated by a greater bowl depth and barrier to bowl inversion in sym-1,3,5,7,9-pentamanisylcorannulene compared to corannulene, an experimental plan is developed to measure the effective hydrogen/deuterium steric kinetic isotope effect (KIE). Symmetry a
