124293-69-2Relevant academic research and scientific papers
A facile synthesis of 1-arenesulfonylazetidines through reaction of 1-arenesulfonylaziridines with dimethylsulfoxonium methylide generated under microwave irradiation
Malik, Sarika,Nadir, Upender K.
, p. 108 - 110 (2008/09/21)
A simple, efficient and general method has been developed for the synthesis of 1-arenesulfonylazetidines through a one-pot reaction of 1- arenesulfonylaziridines with dimethylsulfoxonium methylide, generated under microwave irradiation, using alumina as s
REACTION OF DIMETHYLOXOSULFONIUM METHYLIDE WITH N-ARYLSULFONYLAZIRIDINES - STEREOSPECIFIC CONVERSION OF N-ARYLSULFONYLAZIRIDINES TO N-ARYLSULFONYLAZETIDINES
Nadir, Upender K.,Sharma, Raman L.,Koul, Veerinder K.
, p. 1851 - 1858 (2007/10/02)
Reaction of N-arylsulfonylaziridines with dimethyloxosulfonium methylide leads to the corresponding azetidines stereospecifically ; the cis-aziridines yielding the trans-azetidines and the trans-aziridines furnishing the cis-azetidines.This stereochemical course is interpreted in terms of an SN2-1,4-elimination mechanism.
