1243178-99-5Relevant academic research and scientific papers
Directly Pd(II)-bridged porphyrin belts with remarkable curvatures
Song, Jianxin,Aratani, Naoki,Heo, Ji Haeng,Kim, Dongho,Shinokubo, Hiroshi,Osuka, Atsuhiro
, p. 11868 - 11869 (2010)
A β,β′-doubly 2,6-pyridylene-bridged porphyrin dimer and trimer were prepared by Suzuki-Miyaura coupling reactions and confirmed to have largely bent structures. These oligoporphyrins were readily metalated via meso-C-H bond activation with the assistance of the pyridyl nitrogen atoms to produce the corresponding Pd(II) complexes, which display even larger bent structures and larger TPA values at 800 nm.
