124326-38-1

Basic information

• Product Name: isobutyrophenone enolate
• Synonyms: isobutyrophenone enolate
• CAS NO: 124326-38-1
• Molecular Weight: 147.197
• Mol File: 124326-38-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: isobutyrophenone enolate(CAS DataBase Reference)
• NIST Chemistry Reference: isobutyrophenone enolate(124326-38-1)
• EPA Substance Registry System: isobutyrophenone enolate(124326-38-1)

Safety Data

• Hazardous Substances Data: 124326-38-1(Hazardous Substances Data)

Upstream product

• 611-70-1 phenyl isopropyl ketone 

Downstream Products

• 611-70-1 phenyl isopropyl ketone 
• 281-23-2 adamantane 
• 768-93-4 1-iodoadamantane 
• 120166-56-5 2-methyl-1-phenyl-1-benzoyloxy-1-propene 
• 124286-45-9 2,2-dimethyl-1,4-diphenyl-1,4-butanedione 
• 71491-52-6 2,2,3,3-tetramethylbutyrophenone 

Relevant articles and documents

Radical and Ionic Reactions of (Benzoylmethyl)mercurials

Photolysis of PhCOCH2HgCl or (PhCOCH2)2Hg yields benzoylmethyl radicals which can be trapped by anions such as Me2C=NO2-, RC(CO2Et)2-, RC(O-)=CH2 or by other electron-rich systems such as (RO)3P, N-methylpyrrole, enamines, or norbornene.Electron transfer from the adduct radicals to the mercurials yields PhCOCH2A from the anions A-, PhCOCH2P(O)(OR)2 from P(OR)3, and the phenacyl derivative from N-methylpyrrole or enamines.Easily oxidized anions such as PhCOCPh2- or PhC(CH3)=NO2- react with PhCOCH2* by electron transfer to yield the dimer derived from the anion.Addition of PhCOCH2* to norbornene yields a substituted 3-benzoylpropyl radical which cyclizes at the ortho position of the benzoyl group to give the α-tetralone derivative.