1243581-18-1

Basic information

• Product Name: chloro(tetramesitylporphinato)thallium(III)
• Synonyms: chloro(tetramesitylporphinato)thallium(III)
• CAS NO: 1243581-18-1
• Molecular Weight: 1020.89
• Mol File: 1243581-18-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: chloro(tetramesitylporphinato)thallium(III)(CAS DataBase Reference)
• NIST Chemistry Reference: chloro(tetramesitylporphinato)thallium(III)(1243581-18-1)
• EPA Substance Registry System: chloro(tetramesitylporphinato)thallium(III)(1243581-18-1)

Safety Data

• Hazardous Substances Data: 1243581-18-1(Hazardous Substances Data)

Upstream product

• 56396-12-4 5,10,15,20-tetramesitylporphyrin 

Relevant articles and documents

Synthesis of oligo(p-phenylene)-linked dyads containing free base, zinc(II) or thallium(III) porphyrins for studies in artificial photosynthesis

A series of (p-phenylene)n-linked meso-mesityl-substituted porphyrin dyads (n=2-4) was prepared via Suzuki coupling of zinc(II) and free base porphyrin building blocks. The resulting zinc(II)/free base porphyrin dyads were demetalated. The series of free base porphyrin dimers (n=1-4), four other por- phyrin dimers (with p-phenylene, diphenylethyne or diphenylbutadiyne linkers; and aryl or tridec-7-yl meso substituents), and several benchmark monomers were converted to the thallium(III)chloride complexes under mild conditions. The collection of eight Tl(III)Cl/Tl(III)Cl dimers is designed for studies of ground-state hole-transfer processes and comparison with the excited-state energy- and hole-transfer processes of the corresponding Zn(II)/free base dyads. Altogether, 18 new porphyrin arrays and benchmark monomers have been prepared.