1244030-59-8Relevant articles and documents
Base-catalyzed stereoselective vinylation of ketones with arylacetylenes: A new C(sp3)-C(sp2) bond-forming reaction
Trofimov, Boris A.,Schmidt, Elena Yu,Ushakov, IgoR'A,Zorina, Nadezhda V.,Skital'Tseva, Elena V.,Protsuk, Nadezhda I.,Mikhaleva, AL'Bina I.
supporting information; experimental part, p. 8516 - 8521 (2010/09/05)
Alkylaryl- and alkylheteroarylketones, including those with condensed aromatic moieties, are readily vinylated with arylacetylenes (KOH/DMSO, 100°C, 1 h) to give regio- and stereoselectively the (E)-β-γ- ethylenic ketones ((E)-3-buten-1-ones) in 61-84% yi