124419-75-6

Upstream product

• 66-99-9 β-naphthaldehyde 
• 123324-71-0 p-tert-butylphenylboronic acid 
• 3972-65-4 1-bromo-4-tert-butylbenzene 

Downstream Products

• 124419-95-0 2-Brom-1,3-bis(4-tert-butylphenyl)-1,3-di(2-naphthyl)-1-propen 
• 124419-87-0 1,3-Bis(4-tert-butylphenyl)-1,3-di(2-naphthyl)-1-propen 
• 124419-80-3 (4-tert-Butylphenyl)chlor(2-naphthyl)methan 

Relevant academic research and scientific papers

Rhodium-catalysed aryl transfer to aldehydes: Counterion effects with nitrogen containing ligands

Cationic rhodium complexes of certain nitrogen-containing ligands exhibit excellent activity in the addition of arylboronic acids to aldehydes. The counterion had a notable effect with the weakly coordinating carborane anion affording a highly active catalyst.

Clathrate Formers with Allene Structure - Host Compounds, Crystal Inclusion and Structure of a Dioxane Clathrate

The tetraaryl-substituted allenes 1-8 are synthesized, and their properties in crystal inclusion are determined.Dependent on the type and number of the substituents, host compounds result, which have different inclusion properties and clathrate selectivities.Host 1h forms inclusion compounds with a wide range of apolar and relatively polar cyclic guest solvents (26 inclusions altogether), while 2, 4, 5, and 7b form only one or two inclusions.In two-component solvent systems, high inclusion selectivities are found for the host compounds.The crystal structure of the4*dioxane (1:1) clathrate is reported.Relations between structure and inclusion selectivity are discussed.