124431-77-2

Upstream product

• 123-31-9 hydroquinone 
• 604-69-3 β-D-glucose pentaacetate 
• 106-51-4 p-benzoquinone 
• 3947-62-4 2,3,4,6-tetraacetylglucose 
• 78942-86-6 2,3,4,6-tetra-O-acetyl-1-O-trifluoroacetyl-α-D-glucopyranose 

Downstream Products

• 14698-56-7 4-acetoxyphenyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside 
• 497-76-7 arbutin 

Relevant academic research and scientific papers

Synthesis and G-quadruplex binding study of a novel full visible absorbing perylene diimide dye

A novel perylene diimide dye containing glucopyranosyl groups in 1- and 7-positions of the perylene ring has been synthesized and characterized to obtain highly efficient and stable photosensitized material in photodynamic therapy. Solvatochromic studies

Preparation method of glucoside and derivatives thereof

The invention discloses a preparation method of glucoside and derivatives thereof. According to the method, all hydroxyl groups on a sugar molecule structure are acetylated, a ligand containing phenolic hydroxyl groups is prepared at the same time, then boron trifluoride-diethyl ether is used as a catalyst, the two substances are condensed to obtain tetraacetylated glucoside, and finally acetyl protecting groups are removed to obtain the required glucoside. The method can selectively catalyze hemiacetal hydroxyl of monosaccharide to react with hydroxyl to obtain glucoside, and the product is single. The method is simple in production operation and low in equipment requirement, can be used for synthesizing glucoside and derivatives thereof with similar structures, is green and environment-friendly, and can be used for large-scale production.

Palladium-Catalyzed Chemoselective Negishi Cross-Coupling of Bis[(pinacolato)boryl]methylzinc Halides with Aryl (Pseudo)Halides

We describe a palladium-catalyzed chemoselective Negishi cross-coupling of a bis[(pinacolato)boryl]methylzinc halide with aryl (pseudo)halides. This reaction affords an array of benzylic 1,1-diboronate esters, which can serve as useful synthetic handles f

In the search of glycogen phosphorylase inhibitors: Synthesis of C-D-glycopyranosylbenzo(hydro)quinones - Inhibition of and binding to glycogen phosphorylase in the crystal

Penta-O-acetyl-β-D-glycopyranoses and 1,4-dimethoxybenzene led selectively by electrophilic substitution to C-β-D-glycopyranosyl-1,4- dimethoxybenzenes which were converted by simple and efficient reactions (oxidation, reduction and deacetylation) to the

C-Glycopyranosyl-1,4-benzoquinones and -hydroquinones opening access to C-glycosylated analogs of vitamin E

2-(Per-O-acetyl-β-D-glycopyranosyl)-1,4-dimethoxybenzenes led to C-glycosyl-hydroquinones suitable for preparing C-glycosylated analogs of vitamin E, having the sugar moiety free or acetylated.

Glycosides. Part 1. New Synthesis of 1,2-trans O-Aryl Glycosides, via Tributyltin Phenoxides

A new method of glycosidation of phenols has been studied.The reaction of tributyltin phenoxides 2 with 1,2,3,4,6-penta-O-acetyl-D-hexopyranosides 3, 7 and 9, in the presence of tin tetrachloride is described.Glycosides 4, 8 and 10 have been isolated in g

Studies on glycosides. X. An alternative method for highly stereoselective synthesis of alkyl-β-D-glucopyranosides

An alternate method for the synthesis of alkyl-β-D-glucopyranosides using 2,3,4,6-tetra-O-acetyl-1-O-trifluoroacetyl-α-D-glucopyranose with alcohols or phenols in the presence of Lewis acid at low temperature was reported. β-anomers were the sole product