124475-06-5Relevant articles and documents
Rhodium(II)-catalyzed stereoselective synthesis of allylsilanes
Guptill, David M.,Cohen, Carolyn M.,Davies, Huw M. L.
supporting information, p. 6120 - 6123 (2014/01/17)
The rhodium-catalyzed decomposition of 2-(triisopropylsilyl)ethyl aryl- and vinyldiazoacetates results in the stereoselective formation of Z-allylsilanes. The transformation is considered to proceed by silyl-directed intramolecular C-H functionalization to form a β-lactone intermediate followed by a silyl-activated extrusion of carbon dioxide.