124477-05-0Relevant articles and documents
Fast oxidation of thioglycosides to glycosyl sulfones using KMnO 4/CuSO4·5H2O under neutral reaction conditions
Agnihotri, Geetanjali,Misra, Anup Kumar
, p. 275 - 280 (2007/10/03)
A rapid oxidation of thioglycosides to glycosyl sulfones has been achieved using a combination of KMnO4 and CuSO4·5H 2O in acetonitrile and water. This reaction protocol has many advantages compared to other methods availa
PREPARATION OF PYRANOID GLYCAL DERIVATIVES FROM PHENYL THIOGLYCOSIDES AND GLYCOSYL PHENYL SULPHONES
Fernandez-Mayoralas, Alfonso,Marra, Alberto,Trumtel, Michel,Veyrieres, Alain,Sinay, Pierre
, p. 81 - 96 (2007/10/02)
Phenyl thioglycopyranosides with various protecting groups (acetal, ether, ester) underwent reductive lithiation at C-1, followed by rapid elimination of the 2-substituent, when treated with lithium naphthalenide in tetrahydrofuran at low temperature.Thus