124492-65-5

Upstream product

• 119951-74-5 Benzoic acid (1S,2R,3S,4S,5S)-2,4-diacetoxy-5-acetylamino-3-benzyloxy-cyclohexylmethyl ester 
• 119951-72-3 Benzoic acid (1S,4S,5R,6R)-4,6-diacetoxy-5-benzyloxy-2-nitro-cyclohex-2-enylmethyl ester 
• 68108-50-9 (1S)-(+)-(1,2,4/3,5)-1-acetamido-2,3,4-triacetoxy-5-acetoxymethylcyclohexane 
• 119951-74-5 Benzoic acid (1R,2R,3S,4S,5S)-2,4-diacetoxy-5-acetylamino-3-benzyloxy-cyclohexylmethyl ester 
• 119951-72-3 Benzoic acid (1R,4S,5R,6R)-4,6-diacetoxy-5-benzyloxy-2-nitro-cyclohex-2-enylmethyl ester 
• 64589-26-0 (+/-)-<(1,3/2,4,5)-5-acetamido-2,3,4-triacetoxycyclohexyl>-methyl acetate 
• 119951-73-4 Benzoic acid (1R,2R,3S,4S,5S)-2,4-diacetoxy-5-acetylamino-3-benzyloxy-6-nitro-cyclohexylmethyl ester 
• 119951-73-4 Benzoic acid (1S,2R,3S,4S,5S)-2,4-diacetoxy-5-acetylamino-3-benzyloxy-6-nitro-cyclohexylmethyl ester 

Downstream Products

• 32780-32-8 validamine 
• 68108-50-9 (1S)-(+)-(1,2,4/3,5)-1-acetamido-2,3,4-triacetoxy-5-acetoxymethylcyclohexane 
• 38231-87-7 5-epi-validamine 

Relevant academic research and scientific papers

SYNTHESES OF VALIDAMINE, EPI-VALIDAMINE, AND VALIENAMINE, THREE OPTICALLY ACTIVE PSEUDO-AMINO-SUGARS, FROM D-GLUCOSE

Using as a key reaction a Michael-type addition reaction to nitro-olefins or a substitution reaction for an acetoxyl residue at the β-position of the nitro group in pseudo-nitro-sugar, three optically active pseudo-amino-sugars: validamine, epi-validamine, and valienamine, were synthesized from D-glucose.KEYWORDS--pseudo-amino-sugar optically active; validamine; epi-validamine; valienamine; pseudo-amino-sugar synthesis; Michael-type addition, pseudo-nitro-sugar