124494-63-9Relevant academic research and scientific papers
Interligand interactions dictate the regioselectivity of trans-hydrometalations and related reactions catalyzed by [Cp?RuCl]. Hydrogen bonding to a chloride ligand as a steering principle in catalysis
Rummelt, Stephan M.,Radkowski, Karin,Ro?ca, Drago?-Adrian,Fürstner, Alois
supporting information, p. 5506 - 5519 (2015/05/13)
Reactions of internal alkynes with R3M-H (M = Si, Ge, Sn) follow an unconventional trans-addition mode in the presence of [Cp?Ru(MeCN)3]PF6 (1) as the catalyst; however, the regioselectivity is often poor with unsymmetrica
THE SYNTHESIS OF 1-BENZYLDIMETHYLSILYL-4-PHENYLTHIO-1,3-BUTADIENE: A NEW DIENE-REGENERABLE DIELS-ALDER SYNTHON
Pegram, J. J.,Anderson, C. B.
, p. 6719 - 6720 (2007/10/02)
1-Benzyldimethylsilyl-4-phenylthio-1,3-butadiene (1), prepared by hydrosilation of propargyl alcohol, oxidation and followed by Wittig-Horner reaction, underwent Diels-Alder reaction with methyl methacrylate.The adduct after oxidation to the sulfone when
