124502-79-0Relevant academic research and scientific papers
Regiospecific Enolates from Tetrahydropyran-3-one. Synthetic Equivalents of a Thermodynamically and Kinetically Disfavoured Enolate Isomer
Cox, Paul,Lister, Simon,Gallagher, Timothy
, p. 3151 - 3157 (2007/10/02)
Two synthetic equivalents of the tetrahydropyran-3-one enolate 3 are described.Lithiation of the methoxy enol ether 8b provides the β-lithiated enol ether 10 and although this species does serve as an equivalent of the enolate 3, its use is limited by the
REGIOSPECIFIC TETRAHYDROPYRAN-3-ONE ENOLATES. SYNTHESIS AND REACTIVITY OF SILYL ENOL ETHER DERIVATIVES
Cox, Paul,Mahon, Mary F,Molloy, Kieran C,Lister, Simon,Gallagher, Timothy
, p. 2437 - 2440 (2007/10/02)
The synthesis and reactivity of silyl enol ether (3) is reported.This reagent complements the reactivity of the lithiated enol ether (2) previously used as a synthetic equivalent of the regiospecific tetrahydropyran-3-one enolate (1).
