124512-04-5Relevant articles and documents
2-Amino-5-imino-4,5-dihydrothiazoles: Synthesis by Reaction of Isocyanides with 2-Amino-3-aza-1-thiabutadienes and Base-Induced Rearrangement into Imidazolines or Diazolidines
Morel, Georges,Marchand, Evelyne,Foucaud, Andre,Toupet, Loic
, p. 1721 - 1727 (2007/10/02)
The reaction of isocyanides R3NC with 2-amino-3-aza-1-thiabutadienes 3 gives the 2-amino-5-imino-4,5-dihydrothiazoles 4.The rearrangement of 4 (R2 = H) was induced by 1,5-diazabicyclonon-5-ene and leads to 4H-imidazoline-5-thi