1245209-77-1

Basic information

• Product Name: 2-hydroxy-5-nitrobenzoyl azide
• CAS NO: 1245209-77-1
• Molecular Weight: 208.133
• Mol File: 1245209-77-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-hydroxy-5-nitrobenzoyl azide(CAS DataBase Reference)
• NIST Chemistry Reference: 2-hydroxy-5-nitrobenzoyl azide(1245209-77-1)
• EPA Substance Registry System: 2-hydroxy-5-nitrobenzoyl azide(1245209-77-1)

Safety Data

• Hazardous Substances Data: 1245209-77-1(Hazardous Substances Data)

Upstream product

• 96-97-9 5-nitrosalicylic acid 

Downstream Products

• 36238-80-9 5-nitro-1,2-benzoxazol-3-one 
• 1245209-80-6 2-hydroxy-5-nitrophenylisocyanate 
• 3889-13-2 5-nitro-3H-benzooxazol-2-one 

Relevant articles and documents

Synthesis of benz[d]oxazolones involving concomitant acetyl migration from oxygen to nitrogen

Heating of o-acetoxybenzoyl azides 6-10 in toluene leads to the Curtius reaction, which, when followed by closure of oxazolone ring with concomitant migration of acetyl group from oxygen to nitrogen, produces 3-acetoxybenz[d] oxazol-2(3H)-ones 11-15, which undergo hydrolysis with hot dilute hydrochloric acid to furnish benz[d]oxazol-2(3H)-ones 17-21. Thermal reaction of 2-hydroxy-5-nitrobenzoyl azide (22) in toluene finally yields a mixture of 5-nitrobenz[d]oxazol-2(3H)-one (20) and 5-nitrobenz[d]isoxazol-3(2H)-one (23). Copyright Taylor & Francis Group, LLC.