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Alkaline Hydrolysis of 3-Methyl-2H-1,3-benzothiazinium Iodides
Szabo, Janos,Bernath, Gabor,Sohar, Pal
, p. 789 - 791 (2007/10/02)
Alkaline hydrolysis of the 3-methyl-2H-1,3-benzothiazinium iodide 5a and of its 4-aryl derivatives 5b,c in the presence of hexacyanoferrate(III) ion resulted in the formation of 2,2'-diaryloxodiphenyl disulfides 6a-c.In contrast, the 4-benzyl derivative 5d underwent hydrogen iodide elimination to give the enamine 7.Mechanisms are proposed for the reactions.
