124549-64-0Relevant articles and documents
Total syntheses of (±)-cis- and (±)-trans-neocnidilides
Mahadevegowda, Surendra H.,Khan, Faiz Ahmed
, p. 4400 - 4403 (2014)
Total syntheses of two antimicrobial natural products (±)-cis- neocnidilide and (±)-trans-neocnidilide starting from a readily preparable cyclohexa[b]-fused 5-oxabicyclo[2.1.1]hexane derivative are presented. The diastereomeric tetrahydrofuran tricarboxylate epimers obtained from a BF3·OEt2 promoted Grob-type fragmentation of the oxa-bicycle derivative were converted into title natural products by employing pyridinium dichromate/acetic anhydride mediated bis-oxidative cleavage reaction.