1245570-98-2Relevant academic research and scientific papers
Preparation and reactivity of a ruthenium complex bearing a 2,6-bis(trimethylsilyl)benzenethiolate ligand
Yuki, Masahiro,Miyake, Yoshihiro,Nishibayashi, Yoshiaki
, p. 4148 - 4153 (2010/11/19)
The reaction of [Cp Ru(μ3-Cl)]4 with ArSK (ArS = 2,6-(Me3Si)2C6H3S) gives the mononuclear ruthenium complex with π-arenethiolate ligand [Cp Ru(ν5-SAr)] via [Cp Ru(μ-SAr)]2. Further reactions of [Cp Ru(ν5-SAr)] with HCl and [Cp Ru(μ3-Cl)] 4 give the corresponding monoruthenium complex [Cp Ru(ν6-HSAr)]Cl and diruthenium complex [Cp Ru(μ- ν5:ν1-SAr)RuClCp] in high yields, respectively.
