1245633-79-7Relevant academic research and scientific papers
Formation of acylsilenolates from Bis(acyl)trisilanes as the silicon analogues of acylenolates
Ohshita, Joji,Kawamoto, Hiroyuki,Kunai, Atsutaka,Ottosson, Henrik
, p. 4199 - 4202 (2010)
Reactions of bis(acyl)trisilanes with tris(trimethylsilyl)silyllithium in THF, followed by treatment of the resulting dark red solutions with alkyl halides, gave the Si-alkylated products and tetrakis(trimethylsilyl)silane, indicating the formation of lithium acylsilenolates via Si-Li exchange. Exothermic formation of lithium acylsilenolate was demonstrated by DFT calculations on a model reaction.
