1245654-12-9Relevant academic research and scientific papers
An oxidative coupling for the synthesis of arylated quaternary stereocentres and its application in the total synthesis of powelline and buphanidrine
Bogle, Katherine M.,Hirst, David J.,Dixon, Darren J.
experimental part, p. 6399 - 6410 (2010/10/19)
Catechol derivatives directly bonded to all-carbon quaternary stereocentres are prevalent in nature. An oxidative coupling strategy for the synthesis of this motif is described. Pivoting on the base-catalysed Michael addition of carbon-centred pro-nucleop
