1245728-98-6

Basic information

• Product Name: 3-chloro-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl diethylcarbamate
• Synonyms: 3-chloro-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl diethylcarbamate
• CAS NO: 1245728-98-6
• Molecular Weight: 353.654
• Mol File: 1245728-98-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-chloro-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl diethylcarbamate(CAS DataBase Reference)
• NIST Chemistry Reference: 3-chloro-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl diethylcarbamate(1245728-98-6)
• EPA Substance Registry System: 3-chloro-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl diethylcarbamate(1245728-98-6)

Safety Data

• Hazardous Substances Data: 1245728-98-6(Hazardous Substances Data)

Upstream product

• 159390-33-7 3-chlorophenyl N,N-diethylcarbamate 
• 73183-34-3 bis(pinacol)diborane 

Downstream Products

• 1245729-28-5 3-chloro-5-hydroxyphenyl diethylcarbamate 

Relevant articles and documents

Iridium-catalyzed C-H activation versus directed ortho metalation: Complementary borylation of aromatics and heteroaromatics

Systematic studies are presented demonstrating the complementarity of directed ortho metalation (DoM) and Ir-catalyzed strategies for the provision of borylated aromatics and their subsequent Suzuki-Miyaura coupling reactions. A new concept, the use of the TMS group, readily introduced by DoM, as a latent regiodirective moiety to overcome the otherwise problematic production of isomeric borylated product mixtures is presented. Additional electrophile-induced ipso-deborylation and DoM reactions of the Bpin products are described.