1245809-75-9Relevant academic research and scientific papers
A soluble iron(ii)-phthalocyanine-catalyzed intramolecular C(sp3)-H amination with alkyl azides
Che, Chi-Ming,Fan, Jianqiang,Kang, Fangyuan,Liu, Yungen,Wu, Liangliang,You, Tingjie,Zeng, Si-Hao
supporting information, p. 10711 - 10714 (2021/10/20)
Herein, we describe a soluble iron(ii)-phthalocyanine, [FeII(tBu4Pc)(py)2] (Pc = phthalocyaninato(2-)), as an effective catalyst in intramolecular C(sp3)-H bond amination, with alkyl azides as the nit
Asymmetric transfer hydrogenation of quinolines using tethered Ru(II) catalysts
Parekh, Vimal,Ramsden, James A.,Wills, Martin
experimental part, p. 1549 - 1556 (2010/11/02)
The first report of an asymmetric transfer hydrogenation, in formic acid/triethylamine, of quinolines is described. Using a Ru(II) catalyst containing a 4-carbon tether, products of up to 73% ee were formed, whilst a Rh(III)-tethered catalyst gave products of up to 94% ee.
