1245819-50-4Relevant academic research and scientific papers
Rhodium-catalyzed Asymmetric Arylation of Nitroalkenes Powered by Simple Chiral Sulfur-Olefin Ligands
Wang, Zheng,Chen, Wen-Wen,Xu, Ming-Hua
, p. 331 - 336 (2017/12/04)
An efficient rhodium-catalyzed enantioselective addition of potassium organotrifluoroborates to nitroalkenes powered by simple chiral sulfur-olefin ligands is reported. This protocol is applicable to a broad range of 2-aryl-, alkyl-, and heteroaryl-substituted nitroalkenes, allowing access to diverse chiral β,β-disubstituted nitroethanes in good to excellent yields with high enantioselectivity under mild conditions.
Rhodium-catalyzed asymmetric conjugate addition of organoboronic acids to nitroalkenes using chiral bicyclo [3.3.0] diene ligands
Wang, Zhi-Qian,Feng, Chen-Guo,Zhang, Shu-Sheng,Xu, Ming-Hua,Lin, Guo-Qiang
supporting information; experimental part, p. 5780 - 5783 (2010/10/21)
(Figure Presented) Old before l diene: An efficient rhodium/ diene-catalyzed asymmetric conjugate addition of organoboronic acids to challenging nitroalkene substrates that lack α substituents has been developed. Chiral bicyclo[3.3.0] dienes were found to
