1245833-40-2Relevant academic research and scientific papers
Rhodium(I)-catalyzed [3+2+2]-cyclization of alkenyl Fischer carbene complexes with methyl buta-2,3-dienoate
Barluenga, José,Vicente, Rubén,López, Luis A.,Tomás, Miguel
, p. 6335 - 6339 (2010)
A variety of alkenyl chromium Fischer carbene complexes react with methyl buta-2,3-dienoate in the presence of a rhodium catalyst to afford substituted cycloheptene derivatives 7, along with minor amounts of cyclopentene derivatives 6. Through this [3+2+2]-cyclization two allene units and one alkenyl carbene ligand are assembled in a selective manner.
