124604-13-3Relevant academic research and scientific papers
α-PHOSPHORYL CYCLOPENTANONES AS POSSIBLE INTERMEDIATES IN THE TOTAL SYNTHESIS OF SARKOMYCIN
Mikolajczyk, Marian,Kielbasinski, Piotr,Zurawinski, Remigtusz,Wieczorek, Michal W.
, p. 97 - 100 (2007/10/02)
In an effort to synthesize sarkomycin 1 trans-2-diphenylphosphinoyl-3-tris(methylthio)methyl-cyclopentanone 7 and trans-2-diphenylphosphinoyl-3-carbomethoxy-cyclopentanone 8 were prepared.The Horner-Wittig reaction of the latter with formaldehyde failed.
