1246058-64-9Relevant academic research and scientific papers
Synthesis of Chiral Bitetralin-strapped "Twin Coronet" Porphyrins. Catalytic and Asymmetric Epoxidation of Styrene Derivatives
Naruta, Yoshinori,Ishihara, Nobuo,Tani, Fumito,Maruyama, Kazuhiro
, p. 1933 - 1936 (2007/10/02)
"Twin-coronet" porphyrins bearing optically active 1,1'-bitetrahydronaphthalene derivatives on the both faces of the porphyrin were prepared as enantioselective oxidation catalysts modeling on cytochrome P-450s.The eclipsed isomer of the corresponding iron(III) porphyrins catalyzed epoxidation of styrenes substituted with electron-withdrawing groups in high e.e. (61-89 percent) and high product selectivity.
