124613-28-1Relevant articles and documents
An oxazetidine amino acid for chemical protein synthesis by rapid, serine-forming ligations
Pusterla, Ivano,Bode, Jeffrey W.
, p. 668 - 672 (2015)
Amide-forming ligation reactions allow the chemical synthesis of proteins by the union of unprotected peptide segments, and enable the preparation of protein derivatives not accessible by expression or bioengineering approaches. The native chemical ligati
Carbonyl-inserted organo-hybrids of a Dawson-type phosphovanadotungstate: Scope and chemoselective oxidation catalysis
Oble, Julie,Riflade, Benoit,Noel, Amandine,Malacria, Max,Thorimbert, Serge,Hasenknopf, Bernold,Lacote, Emmanuel
, p. 5990 - 5993 (2012/01/03)
The Dawson-type polyoxometalate (POM) [P2V3W 15O62]9- is a prototype for inclusion of carbonyls of amides, ureas, carbamates, and thiocarbamates into polyoxometallic structures. The carbonyl-inserted POMs catalyze the oxidation of sulfides. Chemoselectivity depends primarily on the proton content of the POM, but it is also influenced by the organic substituent.
Unambiguous Synthesis of 3-Aryloxymethylmorpholine Hydrochlorides Without Ring Enlargement Side Reactions
Brown, George R.,Foubister, Alan J.
, p. 1401 - 1403 (2007/10/02)
The unambiguous synthesis of 3-naphthyloxymorpholine hydrochloride appetite suppressants is reportet.Chemoselective reduction of 4-benzyl-5-oxomorpholine-3-carboxylic acid and its derivatives is described under various metal hydride reducing conditions.