1246213-58-0Relevant articles and documents
Exclusive synthesis of β-alkylpyrroles under indium catalysis: Carbonyl compounds as sources of alkyl groups
Tsuchimoto, Teruhisa,Igarashi, Motohiro,Aoki, Kazuki
supporting information; experimental part, p. 8975 - 8979 (2010/09/09)
No longer difficult: Just mixing readily available carbonyl compounds, pyr-roles, and nucleophiles with an indium catalyst was found to give β-alkylpyr-roles in a regiospecific manner. Removal of benzyl (Bn) and cumyl groups from the nitrogen atoms of the products enables access to nitrogen-unsubstituted β-alkylpyrroles (see scheme).